Electroless Plated Co-Ni-P-B/Ni Foam Catalyst for Hydrogen Generation from Sodium Borohydride.

Abstract

Co-Ni-P-B catalyst supported on Ni foam was prepared using electroless plating for hydrogen generation from an alkaline NaBH4 solution. Co-B, Co-P-B, and Co-Ni-B were prepared for comparison. Surface morphology of catalyst/Ni foams were observed using SEM analysis. The Co- Ni-P-B/Ni foam catalyst showed the superior performance on hydrogen generation rate due to the uniform formation of catalyst particles on the surface of Ni foam. Characteristics of hydrogen generation rate on the Co-N-P-B/Ni foam catalyst were investigated at the variety of NaBH4 and NaOH concentrations. The hydrogen generation rate increased with decreasing NaBH4 concentration, while increasing NaOH concentration. Durability test was performed, resulting in the stable hydrogen generation for 6 hours.