Electrokinetic motion of an electrically induced Janus droplet in microchannels

Abstract

The electrokinetic motion of an electrically induced Janus oil droplet with one side covered with an aluminum oxide nanoparticle film in a circular microchannel was numerically simulated in this paper. The Janus oil droplet is electrically anisotropic as the nanoparticle-covered area carries positive charges and the rest oil–water surface area carries negative charges. A theoretical model was constructed to calculate the electrokinetic velocity of the Janus droplet by considering the force balance on the surface of the Janus droplet at steady state. In the model, the effects of the electric double layer and surface charges on the motion at the oil–water interface are considered. The effects of five parameters on the electrokinetic motion of the Janus droplets were studied: the electric field, the zeta potential ratio of the positively charged side to the negatively charged side of the Janus droplet, the viscosity ratio of the oil phase to the water phase, the nanoparticle coverage of the Janus droplet, and the size ratio of the diameter of the Janus droplet to the diameter of the cylindrical microchannel. The simulation results indicate that the increase in the electrical field, the zeta potential ratio, the viscosity ratio or the nanoparticle coverage leads to faster electrokinetic motion of the Janus droplet. On the other hand, with the increase in size ratio, the electrokinetic velocity of Janus droplet first decreases gradually then increases sharply. The simulated results were compared with the experimental results and good agreement was found.