Abstract
AbstractThe electroinitiated anionic polymerization of p‐diethynylbenzene was carried out in various solvents with different solvation capacity using various electrolytes. The latter were classified depending on their efficiency for the polymerization which was found to be in good agreement with polarographic measurements. IR and H NMR spectral analyses of the polymers obtained showed the formation of extended π‐conjugated systems with only one of the two acetylenic bonds having reacted, thus giving soluble products suitable for structural studies.
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