Abstract
The electrodeposition of tungsten and voltammetric experiments were performed in basic (40-60 mol %) melts containing various tungsten compounds at 450°C. In constant potential electrolysis, metallic tungsten was obtained from and but not from and Similar to the case of acidic melt (60-40 mol %), the oxide ion or an oxochlorotungsten species may participate in the electrodeposition process. The presence of molecular oxygen does not interfere with the process. © 2000 The Electrochemical Society. All rights reserved.
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