Electrodeposition of monodispersed metal nanoparticles in a nafion film: Towards highly active nanocatalysts

Abstract

We have explored a new and facile method for the fabrication of metal nanoparticles on the electrode surface. The approach for fabricating metal nanoparticles was carried out by two steps consisting of ion-exchange in nafion film coated on the electrode and subsequent reduction of metal ions to metallic nanoparticles by electrochemical method. The results of characterization by TEM show that metal nanoparticles were nearly monodispersed in the whole nafion film. The average diameters of Cu, Co and Ni nanoparticles were statistically measured to be 5.1 nm ± 0.2 nm, 4.6 nm ± 0.2 nm and 4.7 nm ± 0.2 nm, respectively. The amount of metal nanoparticles can be readily controlled by the amount of nafion coated on the electrode. By performing the H 2O 2 reduction at the obtained Cu nanoparticles, the high electrocatalytic activity of metal nanoparticles fabricated has been confirmed.