Abstract
The formation of a film of a poorly soluble compound at the surface of metal and indifferent electrodes during the determination of anions and ions of variable valence by stripping voltammetry was considered. A model of the process involves several steps and akes into account the movement of the film-solution interface and the mass transfer through the film. Equations were derived for the estimation of determination limits and the linear portion in theq(c) curve suitable for analytical purposes.
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