Electrodeposited ultra-thin FeCo2O4 nanosheets on nickel foam as binder-free electrodes for high-performance supercapacitors

Abstract

The cobalt-based spinel oxides MCo2O4(M = Ni, Mn, Cu, Fe, etc.) have garnered significant attention due to their potential applications in energy storage. In this study, ultra-thin FeCo2O4 nanosheets have been synthesized through a facile electrodeposition method and used as binder-free electrodes for high-performance supercapacitors. The results indicate that the FeCo2O4 nanosheet (FCS) electrode obtained through 5 min of electrodeposition using ferrous salt (FeSO4) as the precursor has a more abundant pore structure and exhibits the best electrochemical performance. The specific capacitance of the FeCo2O4 nanosheets electrode reaches 679 F g−1 at a current density of 1 A g−1, and it retains 92.9 % of its initial capacitance after undergoing 5000 cycles. In addition, the assembled FeCo2O4 nanosheet (FCS)//activated carbon (AC) asymmetric supercapacitor shows a high energy density of 62.5 Wh kg−1 at 750 W kg−1 and with a capacitance retention of 91.3 % after 5000 cycles. Furthermore, the electrodeposition method utilized in the synthesis of the FeCo2O4 nanosheets is cost-effective, environmentally friendly, and can be employed to fabricate other MCo2O4 materials with superior electrochemical properties.