Electrodeposited porous metal oxide films with interconnected nanoparticles applied as anode of lithium ion battery

Abstract

Controllable synthesis of porous metal oxide films is highly desirable for high-performance electrochemical devices. In this work, a highly porous NiO film composed of interconnected nanoparticles is prepared by a simple co-electrodeposition method. The nanoparticles in the NiO film have a size ranging from 30 to 100nm and construct large-quantity pores of 20–120nm. As an anode material for lithium ion batteries, the highly porous NiO film electrode delivers a high discharge capacity of 700mAhg−1 at 0.2C, as well as good high-rate performance. After 100 cycles at 0.2C, a specific capacitance of 517mAhg−1 is attained. The good electrochemical performance is attributed to the interconnected porous structure, which facilitates the diffusion of ion and electron, and provides large reaction surface area leading to improved performance.