Electrodeposited Heusler Alloys-Based Nanowires for Shape Memory and Magnetocaloric Applications.

Abstract

In this article, the downsizing of functional Heusler alloys is discussed, focusing on the published results dealing with Heusler alloy nanowires. The theoretical information inspired the fabrication of novel nanowires that are presented in the results section of the article. Three novel nanowires were fabricated with the compositions of Ni66Fe21Ga13, Ni58Fe28In14, and Ni50Fe31Sn19. The Ni66Fe21Ga13 nanowires were fabricated, aiming to improve the stoichiometry of previous functional Ni-Fe-Ga Heusler nanomaterials with a functional behavior above room temperature. They exhibit a phase transition at the temperature of ≈375 K, which results in a magnetocaloric response of |ΔSM| ≈ 0.12 J·kg-1·K-1 at the magnetic field change of only μ0ΔH = 1 T. Novel Heusler alloy Ni58Fe28In14 nanowires, as well as Ni50Fe31Sn19 nanowires, are analyzed for the first time, and their magnetic properties are discussed, introducing a simple electrochemical approach for the fabrication of nanodimensional alloys from mutually immiscible metals.