Electrocoagulation/electroflotation of reactive, disperse and mixture dyes in an external-loop airlift reactor

Abstract

This paper studied the efficiency of electrocoagulation/electroflotation in removing colour from synthetic and real textile wastewater by using aluminium and iron electrodes in an external-loop airlift reactor of 20L. The disperse dye is a mixture of Yellow terasil 4G, Red terasil 343 150% and Blue terasil 3R02, the reactive dye is a mixture of Red S3B 195, Yellow SPD, Blue BRFS. For disperse dye, the removal efficiency was better using aluminium electrodes, whereas, the iron electrodes showed more efficiency for removing colour for reactive dye and mixed synthetic dye. Both for disperse, reactive and mixed dye, 40mAcm−2 and 20min were respectively the optimal current density and electrolysis time. 7.5 was an optimal initial pH for both reactive and mixed synthetic dye and 6.2 was an optimal initial pH for disperse dye. The colour efficiency reached in general 90%. The results showed also that Red and Blue disappeared quickly comparatively to the Yellow component both for reactive and disperse dyes. The real textile wastewater was then used. Three effluents were also used: disperse, reactive and the mixture. The colour efficiency is between 70 and 90% and COD efficiency reached 78%. The specific electrical energy consumption per kg dye removed (Edye) in optimal conditions for real effluent was calculated. 170kWh/kgdye was required for a reactive dye, 120kWh/kgdye for disperse and 50kWh/kgdye for the mixture.