Electrocoagulation treatment of paint wastewater from equipment cleaning and conversion of by-product sludge into nano-pigment

Abstract

This work aims to treat paint wastewater from industrial equipment cleaning by electrocoagulation (EC) using aluminum electrodes and reusing residual sludge as a starting material for synthesizing a blue inorganic nano-pigment. An initial pH of the wastewater without adjustment, a current density of 133.33 A/m2, an electrolysis time of 30 min and an inter-electrode distance (IED) of 2 cm were the best operating conditions for EC. The reduction rate of COD and turbidity was about 92% and 99.6%, respectively. At optimum conditions, specific metal consumption and specific electrical energy consumption are about 0.168 kg/m3 and 15 kWh/m3, respectively. The paint wastewater treatment sludge (PWTS) from EC was first characterized and then mixed with cobalt(II) chloride to synthesize an inorganic blue nano-pigment. The effects of Co/Al molar ratios and temperatures were studied. From colorimetric data, the pigment obtained at 1100 °C is more bluish than those synthesized at a lower temperature. This study will have beneficial effects on the environment as well as on the economy because it makes it possible to transform PWTS into value-added products. Treated wastewater can be reused for paint equipment cleaning and EC sludge can be completely transformed into pigment. The zero-waste principle can therefore be achieved.