Abstract

Commercialization of large-area electrochromic glazing is reviewed with respect to device configuration and materials employed. Device configurations including electrochromic solutions and solid state electrochromic layers are discussed as well as novel user-controlled photochromic and gasochromic devices.

Highlights

  • Over the past ten years there has been a dramatic increase in electrochromic (EC) research activity, as seen in the large number of scientific papers and patents issued during this time

  • The least expensive transparent conductors which are currently available are FTO. These are available under the trade names ‘‘TEC’’ and ‘‘Sungate 500’’ from Libbey Owens Ford Industries (LOF)[20] and Pittsburg Plate Glass (PPG)[21], respectively, and from AFG Industries Inc.[22]

  • Nb2O5 is reported to have EC properties which could rival those of WO3, this material has yet to be used as a cathodic EC film in a patented device

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Summary

Introduction

Over the past ten years there has been a dramatic increase in electrochromic (EC) research activity, as seen in the large number of scientific papers and patents issued during this time. Considerable activity is taking place to expand EC technology to larger area applications such as automotive and architectural glazing. This is not an easy task since increasing the size of an EC device involves the combination of many different areas of research which are all interdependent. Sunroofs are most likely to be the first application of EC glazing in automobiles They have the advantage in that because of their location in a vehicle they do not have to comply with the high transmission requirements and they are relatively small, in typical sizes less than 0.7. The different requirements for automotive and architectural glazing are listed in the Table 1

Recent Electrochromic Device Technologies Available
Solution phase electrochromics
Electrochromic devices incorporating solid electrochromic films
Ion storage layer devices
Devices containing both anodic and cathodic electrochromic layers
Electrochromic devices incorporating solution phase redox promoters
Notable new technologies
User controlled photochromic devices
Gasochromic
Current Components Used in Electrochromic Cells
Transparent conductors
Cathodic films
Anodic coloring films and ion storage layers
Electrolytes
Summary
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