Abstract

Metal−Organic Frameworks In article number 2100219, Hidetsugu Shiozawa and co-workers report electrochromism for a family of metal–organic frameworks, M-MOF-74 (M=Mg, Mn, Co or Zn), in which metal cations are coordinated with 2,5-dihydroxyterephthalic acid linkers to form a honeycomb lattice. Raman spectroelectrochemistry combined with density functional theory calculations reveals redox reactions of the linker while the metal cations stay divalent as probed by X-ray photoemission spectroscopy.

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