Abstract
[Mn IIISALEN] + and [Fe IIISALEN] + complexes have been entrapped in the supercages of zeolite Y. The redox properties of these zeolite-encapsulated complexes are investigated by cyclic voltammetry in acetonitrile and dimethyl sulphoxide solutions. The results show the existence of two kinds of entrapped [Fe IIISALEN] + forms within the zeolite. Their existence is related to the mechanism of their preparation and depends on the electrolytic media. The electroactivity of encapsulated Mn-SALEN towards the biomimetic activation of molecular oxygen is discussed.
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