Electrochemically enhanced adsorption of organic dyes from aqueous using a freestanding metal–organic frameworks/cellulose-derived porous monolithic carbon foam

Abstract

Monolithic carbon foams are promising materials for adsorption due to the easy recyclability and without secondary-pollution. However, poor adsorption efficiency for organic pollutants limits its practical application. Hence, this work proposed a novel monolithic porous carbon foam by a facile carbonization approach as freestanding electrodes to remove the organic dyes. The prepared carbon foam derived from waste cigarette filters and zeolitic-imidazolate frameworks-8 with well-developed pores, and the calculated surface area is 1457 m2·g−1, and exhibited an outstanding removal efficiency for methylene blue in aqueous. The maximum adsorption capacity for methylene blue can reach up to 1846.7 mg·g−1 under the applied voltage of −1.2 V. Importantly, as-prepared carbon foams possessed excellent stability, and the removal efficiency can remain above 85% after 5 cycles. Thus, obtained porous carbon foams in this paper as a free standing electrode is expected to be promising materials of adsorbent besides supercapacitors.