Abstract
An efficient decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids using the Langlois reagent as a trifluoromethyl precursor has been achieved by an electro-oxidative strategy. Under catalyst-free and external oxidant-free electrolysis conditions, a series of Cvinyl-CF3 compounds are obtained with a high regioselectivity in good yields. The successful trapping of the CF3 radical by a scavenger has confirmed that radical processes are involved in this system.
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