Abstract
The electrochemical synthesis of tin(II) complexes of catechols, Sn(O2Ar) (1a–9a), have carried out using tin metal as a sacrificial anode in acetonitrile, in the presence of catechol derivatives. The cyclic voltammetric characteristics of the synthesized complexes Sn(O2Ar) (1a–9a) have been studied at glassy carbon electrode in dichloromethane. Anodic oxidation of Sn(O2Ar) produces a single wave which shows irreversibility. Also, the electronic effects of ligands on the redox potential of complexes 1a–9a have been investigated. The synthesis of Sn(O2Ar) species in high yields and purity has been successfully performed in an undivided cell using constant current conditions.
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