Abstract

A novel series of functionalized polythiophenes incorporating 3-(ω-bromoalkyl) pendants are synthesized by electrochemical polymerization. The effect of the solvent on the electrosynthesis is investigated. The polymeric films are characterized using cyclic voltammetry, FT-IR, AFM and SEM microscopy. The poly[3-(6-bromohexyl)thiophene] film cast on GC or ITO electrode surface is compared with a sample obtained by a chemical method.

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