Electrochemical Study on the Macro-Cell Corrosion of Pipeline Steel Partially Covered by Different Kinds of Mineral Deposits.

Abstract

This study presents the impact of mineral deposits (SiO2, Al2O3, and CaCO3) on the corrosion behavior of X65 pipeline steel in CO2-containing brine solution with low pH. The study investigates the initiation and propagation of under deposit corrosion (UDC) using a wire beam electrode (WBE) partially covered by different mineral deposit layers, in conjunction with electrochemical measurements and surface characterization. The results indicate that the corrosion behavior varies, depending on the characteristics of the deposit. During the test period, the Al2O3-covered steel acted as the main anode with more negative potential, while the bare steel acted as the cathode. The SiO2-covered steel acted as the cathode with more positive potential and a localized FeCO3 layer formed beneath the silica mineral. The CaCO3-covered steel initially acted as an anode with a more negative potential but transformed into the cathode at the end of the test. Additionally, shallow and small pits were observed beneath the deposits with the depth in the sequence Al2O3 > SiO2 > CaCO3.