Abstract
The behaviour of the neutral alkynyl complexes trans-[FeBr(L)(depe)2] (L = −C≡C− C(=CH2)Ph 1a, −C≡C−CPh2(H) 1b; depe = Et2PCH2CH2PEt2) is studied by cyclic voltammetry and the electrochemical PL and EL ligand parameters for the alkynyl ligands are estimated showing that they behave as very strong net electron-donors.
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