Abstract
In tetrahydrofuran with 0.2 M NaBPh 4 as supporting electrolyte, the one-electron oxidation at −0.4 V relative to an aqueous saturated calomel electrode (SCE) of the electrogenerated species [Nb(η 5-C 5H 4SiMe 3) 2{ClP(OMe) 3}] ( 3) yields the cationic niobium(IV) complex [Nb(η 5-C 5H 4SiMe 3) 2-Cl{P(OMe) 3}] + ( 4), which has been characterized by ESR spectroscopy. 4 can also be obtained by chemical oxidation of 3.
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