Abstract
A generalization of the molar-ratio method for elucidating the stoichiometry and conditional constant of complex formation from cyclic voltammetry and chronoamperometry is described for systems not accessible by conventional polarographic procedures. Application to complex formation equilibria between [Fe(CN) 6 ] 4- , [Fe(CN) 6 ] 3- , and different polyammonium receptors is discussed. Extension to nonelectroactive complex formation of ATP and carboxylate ions with these receptors by means of the competitive interaction with hexacyanoferrate(II) ion is presented
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