Electrochemical reduction of monothiobenzils in the presence of aroyl chlorides. First synthesis of (Z)-α-benzoyloxy-β-benzoylthiostilbenes

Abstract

The first method for the synthesis of the title compounds has been established involving a stereoselective electrochemical diacylation process. The cathodic reductions of monothiobenzils in an aprotic medium, under constant potential, in the presence of twofold molecular amounts of aroyl chlorides provide previously unknown (Z)-α-benzoyloxy-β-benzoythiostilbenes in high to quantitative yields.