Abstract
The electrochemical studies on a glassy carbon electrode in acetonitrile solutions of dinuclear copper(I) complexes with the general formula [Cu(tmtp)(L)Br] 2, where tmtp = tri- m-tolylphosphine and L = pyridine-2-thione (pyridine-2-thione (py2SH), 1,3-thiazolidine-2-thione (tzdtH), benz-1,3-imidazoline-2-thione (bzimtH 2) and quinoline-2-thione (quintH) have been carried out. The monitoring of the peak position versus scan rate combined with semi-empirical calculations on model compounds provide a suitable method for the characterization of the nature of the bridge formed between the two copper atoms, which may be either sulphur or halogen.
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