Abstract
Electrochemical reactions of various thiols and dithiols have been carried out at sacrificial zinc anode and inert platinum cathode using tetrabutylammonium chloride as supporting electrolyte and acetonitrile as solvent. Solid products separated in the anode compartment have been identified as zinc thiolates and zinc dithiolates. Thc coordination compounds of these thiolates and dithiolates with 1,10-phenanthroline and 2,2'-bipyridine have also been synthesized electrochemically. The solid producis separated in anode compartment were isolated and identified by elemental analysis and infrared spectral data. The current efficiencies of these systems have also been determined which are very high.
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