Abstract

The electrochemical behavior of the concentrated solutions of lithium hexafluoroarsenate in tetrahydrofuran and methyl acetate, having low dielectric constants, was studied. Their high specific conductivity compared with solutions of this ionophore in highly polar solvents (propylene carbonate, γ-butyrolactone) may be due to the additional contribution from the charge transfer by the ionotropic mechanism. Voltammetric curves were obtained on a platinum electrode for LiAsF6 solutions in tetrahydrofuran and methyl acetate. The efficiency of lithium cycling in the systems was evaluated.

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