Abstract
In order to assess the applicability of titanium as a separator material for polymer electrolyte fuel cells (PEFCs), the electrochemical surface characteristics of commercially available pure titanium were examined in a simulated PEFC environment. The results of the electrochemical tests showed that the anode and cathode operating potentials of PEFC, -0.36V and 0.64V (vs.Ag/AgCl(3.33M KCl)), lay in the cathodic and anodic polarization regions for Ti, respectively. Under the PEFC cathode condition, a barrier-type film with high charge transfer resistance and high interfacial contact resistance grew on the specimen. Under the PEFC anode condition, an air-formed oxide film dissolved and an oxidation film with low charge transfer resistance and low interfacial contact resistance grew.
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