Abstract
AbstractThe electrodeposition of palladium from electrolytes containing palladium chloride along with potassium‐dihydrogen phosphate, sodium fluoride or oxalic acid was studied under a variety of condition. The conditions used were: 1.0 M palladium chloride, 0.15 M potassium dihydrogen phosphate, pH 1.5 at 298 K and current density 0.85 mA cm−2/ The current efficiency was calculated and the crystal structure confirmed by X‐ray analysis. Spectrophotomteric and chemical analysis reveals that the purity of the metal is better than 99%. Palladium electrode can function satisfactorily as indicator electrode for hydrogen ions in acid‐base titrations. Titration of acids with sodium hydroxide and of salts of weak acids with hydrochloric acid showed that palladium can indicate very accurately the end point. The end point coincide to great extent with the visual values with an error not more than ± 2%.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
