Electrochemical Performance of Plasma Sprayed Metal Supported Planar Solid Oxide Fuel Cells

Abstract

High production cost is one of the major barriers to widespread commercialization of solid oxide fuel cells (SOFCs). Thermal spray techniques are a low cost alternative for the production of SOFCs. The objective of this work was to evaluate the electrochemical performance of half-cells produced by plasma spraying. The anode was deposited on a porous metallic support by atmospheric plasma spraying (APS) whereas the electrolyte was deposited by plasma spray-thin film (PS-TF) technique which can produce thin and dense coatings at high deposition rates. The cathode was deposited by screen-printing. The electrochemical tests were performed at 650-800°C. Current-voltage characteristics and impedance spectra were measured and analyzed. The impact of electrolyte composition and layer thickness on the gas tightness of the electrolyte and the area specific resistance of the cell is discussed. The results show that the applied thermal spraying techniques are a potential alternative for producing SOFCs.