Electrochemical performance of metal nitride coated titanium bipolar plate for proton exchange membrane water electrolyser

Abstract

In order to improve corrosion resistance and electric conductivity of titanium bipolar plate (BPP) for proton exchange membrane water electrolyser (PEMWE), three different metal nitride (i.e.Ta/TaN, Cr/CrN and Nb/NbN) coated titanium bipolar plates are prepared by magnetron sputtering. The coated BPP is characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscope (AFM), and their electrochemical performance is assessed by electrochemical corrosion tests including open circuit voltage (OCP), potentiodynamic and potentiostatic polarization tests in the simulated PEMWE anode environment. It is revealed that the surface roughness of titanium substrates is decreased after coating, implicating the reduced interfacial contact resistance (ICR). Potentiodynamic and potentiostatic tests demonstrate that Ta/TaN and Nb/NbN coatings can significantly improve the corrosion resistance of titanium bipolar plate. The corrosion current density of coated substrate is reduced by approximately 67 % upon coating with Ta/TaN and Nb/NbN under the simulated PEMWE anode environment. However, the ICR of Ta/TaN coating is the lowest (3.9 mΩ × cm2), which is reduced by 74 % compared with pristine titanium substrate (14.9 mΩ × cm2). Hence, the Ta/TaN coated BPP is tested in single electrolytic cell and demonstrates significantly improved electrolysis efficiency.