Abstract

The results obtained from approximately 4000 h of operation of an electrochemical oxygen meter developed at General Electric Company for measuring oxygen activities in liquid sodium are described. In the present design, a small ceramic cup (ThO/sub 2/ with 7 to 8 wt % Y/sub 2/O/sub 3/) has been brazed to a metal tube that is inserted into the liquid sodium via a standard sodium flange. The reference electrode used in the present design consists of In/In/sub 2/O/sub 3/. Several meters were tested in a flowing sodium system, where the oxygen concentrations were controlled by a cold trap. At 500/sup 0/C, the oxygen electromotive force (emf) output can be expressed as emf/sub (V)/ = 0.269 + (160/T) (+-0.003 V), where T is the cold-trap temperature in K. The temperature coefficient of the meters can be expressed as (dE/dT) = 0.51 +- (0.02) mV//sup 0/C.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.