Abstract
The polarographic behavior of N,N-dimethylaniline, triphenylamine, diphenylamine, and di-4-tolylamine has been studied in acetonitrile medium on a rotating platinum electrode. It has been found possible to apply the oxidation waves of these substances to their polarographic determination, considering the water content of the solvent, temperature and acidity of the medium. Constant current coulometric generation has been used to study the number of electrons exchanged in the reactions. The products formed in the electrode reaction are discussed.
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