Abstract
Linear voltammetry in the potentiodynamic mode is used to study the electrochemical behavior of a heavy tungsten-containing VNZh alloy (in wt %: 90 W, 7 Ni, 3 Fe) and its components in ammonia–alkali electrolytes. The anodic oxidation of individual tungsten and nickel is found to be activated when NH4OH is introduced into the composition of an alkaline electrolyte. Galvanostatic electrolysis is used to perform electrochemical processing of a VNZh-type alloy with a current efficiency of about 100% for tungsten and a specific energy consumption of ~1.5 kW h/kg.
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