Abstract

Classical and atomistic nucleation models have been tested in several aqueous systems dealing with electrocrystallisation. A lot of reported experimental nucleation data have been used and in a wide range of overpotentials. The critical nucleus size has been calculated in those cases not reported in the original work, and the results obtained with the classical and atomistic models have been tabulated, compared and discussed. Small values for the critical nucleus size occur in most of the systems.

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