Abstract
Abstract The catalytic methyl-transfer reaction from methyl tosylate to 1-octanethiol was carried out in the presence of heptamethyl cobyrinate perchlorate, hydrophobic vitamin B12, under electrochemical conditions at −1.0 V vs. Ag/AgCl using a carbon-felt cathode and a zinc plate anode as the sacrificial electrode in an undivided cell. This catalytic reaction proceeded via the formation and dissociation of the cobalt–carbon bond in the hydrophobic vitamin B12.
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