Abstract
In the process of finding new forms of energy extraction or recovery, the use of various natural systems as potential clean and renewable energy sources has been examined. Blue energy is an interesting energy alternative based on chemical energy that is spontaneously released when mixing water solutions with different salt concentrations. This occurs naturally in the discharge of rivers into ocean basins on such a scale that it justifies efforts for detailed research. This article collects the most relevant information from the latest publications on the topic, focusing on the use of the mixing entropy battery (MEB) as an electrochemical ion pumping device and the different technological means that have been developed for the conditions of this process. In addition, it describes various practices and advances achieved by various researchers in the optimization of this device, in relation to the most important redox reactions and the cathode and anodic materials used for the recovery of blue energy or salinity gradient energy.
Highlights
Increasing energy demand and excess pollution, because of the use of fossil fuels, has created the necessity to generate clean energy using available natural resources, precluding the use of fuels derived from petroleum
In 1954, was the first to propose the mixture between river water and seawater as an interesting alternative renewable energy source, with an electrochemical device called the Hydroelectric
A mixing entropy battery device consists of a reversible electrochemical system, where the electroactive ions present in the natural solution are pseudo capacitively stored in their respective electrodes
Summary
Increasing energy demand and excess pollution, because of the use of fossil fuels, has created the necessity to generate clean energy using available natural resources, precluding the use of fuels derived from petroleum. These natural resources include solar, wind, geothermal and biomass being already utilized in various extents. The ocean is another inexhaustible source of renewable energy, highlighting the use of energy from waves, tide, ocean currents, offshore winds, the thermal gradient of the ocean and different salinity concentrations between two solutions, such as seawater and river water [1]. The objective of this review is as follows: (a) To present the theoretical background and recent advancements in mixing entropy batteries through an overview of the state of the art and most recent technological advances; and (b) To describe materials for these batteries together with major challenges in the technology and the need for fundamental research prior to its world-wide deployment
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