Electrochemical investigation of MnO 2 electrode material for supercapacitors

Abstract

MnO 2 electrode material is synthesized by low temperature solid state reaction between KMnO 4 and MnCl 2. Effects of the KMnO 4:MnCl 2 molar ratio on the structure, morphology and electrochemical properties of the as-prepared sample were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical tests. Results showed that the obtained MnO 2 is α-MnO 2, the average diameter is about 0.5–1.5 μm, which are constituted of nanoparticles of 20 nm. Under 100 mA g −1, the specific capacitances of the prepared sample is 258.7, 219.6, 215.3, 198.5 and 209.5 F g −1 at the KMnO 4/MnCl 2 molar ratio of 3:2, 2:1, 1:1, 1:2 and 2:3, respectively. And the MnO 2 sample with a KMnO 4/MnCl 2 molar ratio of 3:2 exhibits the best discharge capacitance and cycle performance. When the charge/discharge rate increases to 300 mA g −1, the sample still remains initial discharge capacitance of 165.3 F g −1, and the discharge capacitance is 145.9 F g −1 after 200 cycles, the capacitance retention rate is 102.4% during the 20–200th cycles. Therefore, the MnO 2 sample is an excellent material for use in supercapacitors because of its large specific capacitance and good cycle performance.