Electrochemical impedance spectroscopy study of corrosion characteristics of palladium-silver dental alloys.

Abstract

Electrochemical impedance spectroscopy (EIS) has been used to obtain insight into corrosion processes for three Pd-Ag alloys, and compare their behavior with an Au-Pd alloy. Five specimens of each alloy received clinically-appropriate simulated porcelain-firing heat treatment. EIS testing was performed at ambient temperature, using 0.09% NaCl, 0.9% NaCl and Fusayama solutions. EIS data are presented as Bode plots. At the open-circuit potential (OCP), the data fit a modified Randles equivalent electrical circuit with a constant phase element (CPE), and the charge-transfer resistance (RCT ) and the two CPE parameters (CPE-T and CPE-P) were determined. The area-normalized capacitance of the double layer (Cdl ) was also calculated. The EIS data at two relevant elevated potentials in the passive range were also found to fit well a modified Randles equivalent circuit with different values for the charge transfer resistance and CPE parameters. At the OCP no significant effect on RCT was found for the alloys and electrolytes, and both alloy and electrolyte significantly affected CPE-P. In vitro corrosion was controlled by charge transfer and charge accumulation processes, and the behavior differed at the elevated potentials compared to the OCP. Significant effects were found for alloy, electrolyte, and alloy/electrolyte interaction on Cdl at the OCP. The EIS parameters at elevated potentials indicate that the Pd-Ag alloys should have satisfactory clinical corrosion resistance. The EIS analyses yielded information about in vitro corrosion of these alloys that cannot be obtained from potentiodynamic polarization testing.