Electrochemical Impedance Spectroscopy of Core‐Shell Nanofiber Cathodes, with Ce0.9Gd0.1O1.95 (Core) and Cu‐Doped La0.6Sr0.4MnO3 (Shell), for Application in Solid Oxide Fuel Cells

Abstract

AbstractSeveral core‐shell nanofiber electrodes are prepared through electrospinning and tested for application as intermediate‐temperature solid oxide fuel cell (IT‐SOFC) cathodes. The materials investigated are La0.6Sr0.4MnO3 (LSM), La0.6Sr0.4Cu0.1Mn0.9O3‐δ (LSCuM_1), and La0.6Sr0.4Cu0.2Mn0.8O3‐δ (LSCuM_2) perovskites, used at the shell side of the nanofibers. Ce0.9Gd0.1O1.95 (GDC10) fluorite is used as the core material. The electrochemical characterization of the core‐shell nanofiber electrodes is performed through electrochemical impedance spectroscopy (EIS). The EIS results are reported and discussed based on equivalent circuit modeling. The polarization resistance of the GDC10/LSM core‐shell nanofibers electrodes is RP∼4.5 Ω cm2 at 650 °C. Improvement is accomplished with GDC10/LSCuM_1 and GDC10/LSCuM_2 core‐shell nanofibers, with RP∼1.8 Ω cm2 and 1.7 Ω cm2 respectively at 650 °C. Post‐test SEM characterization is carried out, to ascertain possible degradation and identify the most promising shell perovskite.