Abstract

The development of simple and green strategies for preparing non-precious metal electrocatalysts is significant for renewable energy storage technologies. We report in this work the fabrication of hierarchical CoP microflowers (HMF CoP) assembled with nanosheets through an electrochemical exfoliation followed by the subsequent optimized phosphorization process. Thanks to hierarchical micro/nanostructure, strong electron interactions between Co and P atoms, large specific surface area (131.31 m2 g−2), and enriched active sites, the as-prepared CoP electrocatalyst exhibits excellent performance with driving a current density 10 mA cm−2 at a low overpotential of 106 mV, a small Tafel slope of 44.5 mV dec−1, and satisfactory durability after 20 h HER testing at 10 mA cm−2. This work would develop a newfangled strategy to design more non-precious metal nanomaterials as high-efficiency electrocatalysts.

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