Abstract
Abstract In order to better understand the low faradic yield of low temperature fluorinated graphite used as electrode in primary lithium batteries, a study of the discharge mechanism has been performed. The evolution of some physico-chemical parameters such as C–F bond nature and structure of the fluorocarbon matrix has been determined by X-ray diffraction, solid state 19 F NMR and EPR as a function of the depth of discharge. The influence of residual catalytic species on electrochemical properties will be also discussed.
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