Abstract

An efficient and practical electrochemical method for the three-component reaction cascade Mumm rearrangement of imides has been developed using a simple undivided cell with carbon electrodes at room temperature, which provides a useful strategy for the rapid synthesis of sulfur-containing imides with broad substrate scope and high functional tolerance. It is a rare example of in situ generation of O-acyl isoamide precursor for Mumm rearrangement.

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