Abstract

In recent years, alloy and alloy-ceramic coatings have gained a considerable attention owing to their favorable physicochemical and technological properties. In this review, we investigate Ni, NiCo alloy and NiCo–ceramic composite coatings prepared by electrodeposition. Electrodeposition is a versatile tool and cost-effective electrochemical method used to produce high quality metal coatings. Surface finish and tribological properties of the coatings can be further improved by the addition of suitable agents and control of deposition operating conditions. In this review, Ni, NiCo alloy and NiCo–ceramic composite coatings prepared by electrodeposition are reviewed by critically evaluating previous researches. The use of the coatings and their potential for future research and development are discussed.

Highlights

  • Materials are a fundamental pillar in engineering technology

  • To further improve the properties of Ni–Co alloy coatings, nanoparticles have been suspended in electrolyte and they become embedded into the electro-formed solid phase layer during electrodeposition [23]

  • The two main forces at work during sediment codeposition (SCD) electrodeposition are gravitational pull and the electrophoresis force, thereby giving more desirable properties compared to conventional deposition which solely relies on gravitational pull [30]

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Summary

Introduction

Materials are a fundamental pillar in engineering technology. The materials’ electrochemical, thermal and mechanical interaction begins on the surface. To further improve the properties of Ni–Co alloy coatings, nanoparticles have been suspended in electrolyte and they become embedded into the electro-formed solid phase layer during electrodeposition [23] In such materials, the inherent properties of the nanoparticles have been found to significantly influence the overall properties of the nanocomposite coatings. Many different types of nanoparticles have been electrodeposited with Ni–Co alloy including SiC, Al2 O3 , SiO4 , ZrO2 , Cr2 O3 , Si3 N4 and TiO2 [24] These nano particles used in electrodeposition can be classified as either hard materials or soft materials depending on the desired properties. Properties such as adhesion between substrate and coating have been extensively discussed, comparisons between techniques drawn, and recommendations for further adhesion improvement have been presented

Direct Current Electrodeposition
Pulse Current Electrodeposition
Jet Electrodeposition
Schematic
Effect of Co Concentration in Electrolyte
Current Density
Particle Content
Electrolyte Agitation
Temperature
Electrolyte pH
Pulse Frequency
Duty Cycle
Mechanism
Baths Used in Electrodeposition Process for Ni–Co Coating
Chloride Baths
Sulfate Baths
Sulphamate Baths
Additives
Boric Acid
Surfactants
Saccharin
SEM micrographs of Ni–Co
Mechanical Properties
Corrosion Behaviour
NiCo–Ceramic Composites
Effect of Al2 O3 Nanoparticles
Effect of SiC Nanoparticles
Effect of ZrO2 Nanoparticles
Applications
Findings
10. Future Scope and Recommendations
Full Text
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