Electrochemical degradation of RB-5 dye by anodic oxidation, electro-Fenton and by combining anodic oxidation–electro-Fenton in a filter-press flow cell

Abstract

This paper reports the removal of a recalcitrant and toxic dye, Reactive Black 5 (RB-5) by three methods; 1) anodic oxidation (AO) on Boron-Doped Diamond (BDD), 2) by electro-Fenton (EF) process where hydrogen peroxide was produced by oxygen reduction on reticulated vitreous carbon (RVC) electrodes and 3) by the combination of AO–EF. The BDD and RVC electrodes were fitted in a filter-press flow cell in recycle batch mode of operation. The experimental set-up for the AO and EF processes consisted of two electrolyte compartments separated by a Nafion membrane with the dye contained in the anolyte and the catholyte, respectively. The combined AO–EF process used only one electrolyte compartment. The colour and total organic carbon (TOC) removal were more efficient when the AO and EF processes were used separately than the combined process, AO–EF. The influence of current density and initial concentration of ferrous ions were examined. The lowest energy efficiency (208kWhkg−1) with the EF process was found when −0.4V vs. Ag/AgCl was applied to a RVC electrode and the concentration of Fe2+ was 1.0×10−4moldm−3 achieving total colour and 74% of TOC removals in less than 90min electrolysis. All proposed processes were able to promote high percentages of TOC removal following a pseudo-first order kinetic oxidation. The BDD electrode was the most effective material to remove RB-5 dye within 7.5min and presented the highest apparent rate constant (0.835min−1) with 82% TOC removal within 30min at an energy consumption of 291kWhkg−1 and 41.1mAcm−2 current density. In the case of the combined process AO–EF the electrodegradation rate of RB-5 was at least three times lower, apparent rate constant (0.269min−1), and 32% of TOC was removed with a high EC (682kWhkg−1). Therefore oxidation process applied separately was more efficient.