Abstract
New conducting copolymers have been synthesized via electrochemical oxidation of thiophene (Th) in the presence of monomer bis(2-thienyl)ethyl ( I). Cyclic voltammetry (CV) studies showed that the presence of monomer I in the electrolytic solution greatly changes the CV behaviour of the formation of the polythiophene films. It is found that the increasing ratio of I was found to decrease electroactivity of copoly( I-Th). Electrochemical synthesis of copolymer films was achieved via constant potential electrolysis (CPE) in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF 6) dissolved in CH 3CN. Spectroelectrochemical (SPEL) properties of the films were investigated using UV–vis spectroscopic technique.
Published Version
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