Abstract

A model describing the electrochemical charging of Pd rods is presented. The essential feature of this model is the coupling of the interfacial processes with the transport of interstitials in the electrode interior. It is shown that boundary conditions arise from the solution of equations governing the elementary adsorption-desorption and adsorption-absorption steps and the symmetry of the electrode. Effects of the choice of rate constants of the elementary steps and the charging current on the surface coverage, the electrode potential and the time required to complete electrode charging are examined.

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