Abstract
In this article, experimental methods based on cyclic voltammetric technique were used to study the electrochemical analysis of a new modified electrode with zirconium dioxide molecules on the glassy carbon electrode (ZrO2NPs/GCE) to characterize iron ions K4[Fe(CN)6]. These methods also allowed the study of current peaks for oxidation reduction of Fe(II)/Fe(III) using potassium chloride (KCl) solution as electrolytes at different concentration, pH, scanning rates, and stability (reliability) of which these parameters are important in assessing oxidation properties. Also, the diffusion coefficient values of oxidation-reduction reaction for iron ions on the new sensor (ZrO2 NPs/GCE) was determined using Randles-Seveik equation as Dfa = 2.03 ×10-5 cm2 /sec and Dfc = 7.12 × 10-5 cm2 /sec, respectively. It was found the modified electrode ZrO2NPs/GCE acts as a good sensor with high detection limit of iron ions in electrolyte. It can be used the modified electrode in different electrochemical applications because of its higher conductivity.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
