Electrochemical characteristics of partially cobalt-substituted LiMn2−yCoyO4 spinels synthesized by Pechini process

Abstract

Un-substituted LixMn2O4 with various Li/Mn ratios and Co-substituted LiMn2−yCoyO4 spinels were prepared by the Pechini method. The precursors were calcined at 200°C for 6h followed by heat-treatment at 800°C for 8h. Crystalline structure and electrochemical characterization of the synthesized cathode materials for lithium batteries had been studied. The Co-substituted spinels showed an improvement on the cycling properties over the un-substituted one. Among the Co-substituted spinels, LiMn1.8Co0.2O4 exhibited the most promising cycling performance with initial specific discharge capacity of 110mAhg−1 and fading rate of 0.5mAhg−1 per cycle (or 0.45% per cycle). The improvement in cycling performance might be contributed by the stabilization of the spinel structure by smaller lattice constant when manganese ion was partially substituted by Co3+ ion.