Abstract
The synthesis and electrochemical characterisation of the following oxotitanium tetra-substituted phthalocyanines are reported: 1,(4)-(tetrabenzyloxyphthalocyaninato)titanium(IV) oxide ( 5a); 1,(4)-{tetrakis[4-(benzyloxy)phenoxy]phthalocyaninato}titanium(IV) oxide ( 5b); 2,(3)-(tetrabenzyloxyphthalocyaninato)titanium(IV) oxide ( 6a) and 2,(3)-{tetrakis[4-(benzyloxy)phenoxy]phthalocyaninato}titanium(IV) oxide ( 6b). The electrochemical characterisation of complexes octa-substituted with 4-(benzyloxy)phenoxy ( 9b), phenoxy ( 9c) and tert-butylphenoxy ( 9d) groups is also reported. The cyclic voltammograms of the complexes exhibit reversible couples I– III and couple IV is quasi-reversible for complexes 5a, 5b, 6a and 6b. The first two reductions are metal-based processes, confirmed by spectroelectrochemistry to be due to Ti IVPc 2−/Ti IIIPc 2− and Ti IIIPc 2−/Ti IIPc 2− redox processes and the last two reductions are ring-based processes due to Ti IIPc 2−/Ti IIPc 3− and Ti IIPc 3−/Ti IIPc 4−. Chronocoulometry confirmed a one-electron transfer at each reduction step. The electrochemistry of the above complexes is also compared to the previously reported 5c, 5d, 6c and 6d.
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