Abstract
The electrochemical behaviour of iron(II), nickel(II) and copper(II) complexes with a number of derivatives of the pentadentate ligand bis(salicylideneimine-3-propyl)amine (X-SALRDPT) has been investigated in non-aqueous solvent. The one-electron anodic oxidation of all the metal(II) complexes has been characterized and correlated, as well as the frequency shifts of their d–d transitions, to the inductive effect of the various substituents on the salicylic moieties. Crystal field stabilization energies involved in the redox change are discussed. The cathodic charge transfer II/I and I/0 for nickel(II) and copper(II) chelates have been also investigated. On the basis of electrochemical measurements, some considerations on the reactivity of the complexes towards dioxygen are made.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
